Hitting a valve is such a common way of blowing veins. This happens because valves are stronger than vein walls, so when you advance your catheter, hit a valve, then keep advancing, it will often push out the side of the vein or cause so much damage to the wall that the vein blows.
When you’re palpating, try to feel for valves along the vein you want to cannulate. Valves are almost always found at a vein junction (bifurcation), and can feel like a slight bulge in the vein where it is otherwise straight and smooth. When you advance your catheter, try to advance it slowly, and stop at the first sign of resistance which would likely be caused by a valve. If you feel resistance and can no longer advance, STOP, remove your tourniquet, remove your needle, hook up your tubing with saline flush, then flush the IV while advancing the catheter. This will open the valve and allow the catheter to pass through. Once the catheter is fully advanced, pull back on the syringe and re-check for blood return to make sure it is still inside the vein.